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There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

The composition ratio of saturated and unsaturated fatty acid methyl esters (FAME) is depended on feedstock. Three FAMEs: soybean (SME), palm (PME) and coconut oil (CME) methyl esters were mixed to make fuels which have different composition ratio. The ignitability of fuel which mainly consisted of unsaturated FAME was inferior. Power was slightly reduced with increasing of mixing ratio of CME; however exhaust gas emissions were improved because CME contained a lot of oxygen atoms. Fuel which was equal mixture SME and CME indicated almost the same ignition characteristic as that of PME because they have same composition ratio.

DME is alternate fuel for diesel engines, however DME has defects such as small lower calorific value, inferior lubricity and weak fuel penetration. To compensate disadvantages, In-direct injection 2-stroke diesel engine with low pressure fuel injection system was proposed. The fuel injection timing near TDC gave good performance because the heat loss of low temperature oxidation reaction reduced. The brake torque and brake thermal efficiency of 2-stroke IDI diesel engine were lower than those of 4-stroke engine. However, the exhaust gas emissions were very low level because the intake air leaked through the exhaust port and the exhaust gas was diluted.

A new bio-fuel i.e. the cellulosic liquefaction fuel (CLF) was developed for diesel engines. CLF was made from woods by direct liquefaction process. When neat CLF was supplied to diesel engine, the compression ignition did not occur, so that blend of CLF and diesel fuel was used. The engine could be operated when the mixing ratio of CLF was up to 35 wt%. CO, HC and NOx emissions were almost the same as those of diesel fuel when the mixing ratio of CLF was less than 20 wt% whereas the thermal efficiency slightly decreases with increase in CLF mixing ratio.

The coconut-oil methyl ester is made from coconut oil and methanol, and both cold start performance and ignition characteristics of coconut-oil methyl ester are experimentally investigated by using a diesel engine. In experiments, diesel fuel and coconut-oil methyl ester are used and the blended ratio of coconut-oil methyl ester to diesel fuel is changed. The test is conducted at full load and 3000 rpm. The diesel engine can be run stably with any mixing ratio of coconut-oil methyl ester, however the power is slightly reduced with increasing the mixing ratio of coconut-oil methyl ester. In the cold start condition, when the mixing ratio of coconut-oil methyl ester increases, the combustion chamber wall temperature rises early and the ignition timing is improved. Therefore, the coconut-oil methyl ester has superior compression ignition characteristics and reduces exhaust gas emissions, so that the coconut-oil methyl ester is good alternative fuel for diesel engines.

Attention has recently been focused on homogeneous charge compression ignition combustion (HCCI) as an effective combustion process for resolving the essential nature of combustion. Meanwhile, dimethylether (DME) has attracted interest as a potential alternative fuel for compression ignition engines. Authors measured the combustion process of DME HCCI by using a spectroscopic method. A diesel engine was used as the test engine. The results of these analyses showed that changes in the compression ratio, intake air temperature and equivalence ratio influenced the ignition timing in the HCCI combustion process. This paper discusses these effects in reference to the experimental and calculated results.

Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition. Light emission intensity was measured at wavelengths of 306.4 nm (characteristic spectrum of OH), 329.8 nm (HCO), 395.2 nm (HCHO). A four-cycle, air-cooled, single-cylinder gasoline engine with a side valve arrangement was used as the test engine. Light emission behavior was simultaneously observed at two positions (the end zone and the center zone) in the combustion chamber. The test fuel used was n-heptane (0 RON). The test engine was operated at three speed levels (1400, 1800 and 2200 rpm). As a result, preflame reactions were observed. It was also observed that the tendencies seen for the preflame reaction interval varied depending on the engine speed.

In this study, the heated fuels were provided to the diesel engine in order to activate the fuel before the injection. Two test fuels: the normal diesel fuel and cetane, which have different boiling points were used. For both normal diesel fuel and cetane, crank angles at ignition and maximum pressure are delayed and the maximum combustion pressure is decreased as the fuel temperature rises. In cases of large and middle mass flow rate of fuel injection, the brake thermal efficiency and brake mean effective pressure are decreased when the fuel temperature is higher than 570 [K]. However, in the case of small mass flow rate of fuel injection, the brake thermal efficiency is almost independent of fuel temperature. HC and CO concentrations in the exhaust gas emission show constant values regardless of fuel temperature. However, NOx concentration is gradually decreased as the fuel temperature rises.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

In this research, the effect of high-temperature residual gas, resulting from the application of a certain level of EGR, on combustion was investigated using a two-stroke engine and alcohol fuels (ethanol and methanol) and gasoline as the test fuels. Measurements were made of the light emission intensity of the OH radical on the intake and exhaust port sides of the combustion chamber and of the combustion chamber wall temperature (spark plug washer temperature) and the exhaust gas temperature. Data were measured and analyzed in a progression from normal combustion to autoignited combustion to preignition and to knocking operation.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by direct diesel fuel injection. In this study, the internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the temperature of the mixture before the ignition. It is confirmed that the lean methanol-air mixture of air-fuel ratio between 130 and 18 could be ignited and burned when the back pressure of 80 [kPa] is added. The ignition and combustion characteristics can be improved by the internal EGR, however the engine performance and NOx emission deteriorated.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. The internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the mixture temperature. The test engine was a 4-stroke, single- cylinder direct-injection diesel engine. The cooling system was forced-air cooling and displacement volume was about 211 (cm3). The compression ratio was about 19.9:1. The experiment was made under constant engine speed of 3000 (r/min). The boost pressure was maintained at 101.3 (kPa). Five values of mass flow rate of diesel fuel injection were selected from 0.060 (g/s) to 0.167 (g/s) and five levels of back pressure: 0), 26.7, 53.3, 80.0 and 106.6 (kPa) were selected for the experiment. The effect of internal EGR is varied by the back pressure level.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

The uniform lean gasoline-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. In this study, the internal EGR is add to this ignition method in order to activate the fuel in the mixture before the ignition. It is confirmed that the lean mixture of air-fuel ratio between 150 and 40 could be ignited and burned by this ignition method when the back pressure of 80 [kPa] is added, and the burning period is shorted by internal EGR. However, as the back pressure increases, NOx concentration is increased by the high temperature residual gas.

The uniform lean gasoline-air mixture was provided to diesel engine and was ignited by direct diesel fuel injection. The mixing region that is formed by diesel fuel penetration and entrainment of ambient mixture is regarded as combustible turbulent jet. The ignition occurs in this region and the ambient lean mixture is burned by flame propagation. The lean mixture of air-fuel ratio between 150 and 35 could be ignited and burned by this ignition method. An increase of diesel fuel injection is effective to ensure combustion and ignition. As diesel fuel injection increases, HC concentration decreases, and NOx and CO concentration increases.

The use of a higher compression ratio is desirable for improving the thermal efficiency and specific power of spark-ignition engines, but it gives rise to a problem of engine knock. In the present research, an investigation was made of the role of the preflame reaction region of a spark-ignition engine in the occurrence of autoignition. Emission spectroscopy was used to measure the behavior of formaldehyde (HCHO) in a cool flame. In addition, measure the behavior of the faint light attributed to the HCO radical in a blue flame with the concurrent measurement of the OH radical. The emission waveforms measurements obtained for HCHO when n-heptane (ORON) was used as the fuel, It is thought that these tendencies correspond to the passage and degeneracy of a cool flame. Further, the emission waveforms measured for the HCO radical when blended fuels (6ORON, 8ORON) were correspond to that of a blue flame.

Emission intensity was measured at a wavelength of 395 2 nm (corresponding to the characteristic spectrum of the HCHO radical) and absorbance was measured at 306 4 nm (corresponding to that of the OH radical). The emission intensity and absorbance waveforms recorded during engine operation on n-heptane show behavior indicative of the passage and degeneracy of cool flame in the preflame reaction interval. As the combustion chamber wall temperature approached an overheated state in the transition from normal combustion to knocking operation different preflame reaction behavior was observed which is thought to correspond to the presence of a negative temperature coefficient region related to the ignition delay time.